A novel synthesis of highly stable palladium nanoparticles and their application in the reduction of nitroaromatic compounds

Othman Abdullah, Fuad (2021) A novel synthesis of highly stable palladium nanoparticles and their application in the reduction of nitroaromatic compounds. Materials Research Express, 8 (9). pp. 1-9.

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Official URL: https://iopscience.iop.org/journal/2053-1591

Abstract

Herein, a mild and efficient method for synthesis of highly stable palladium nanoparticles (PdNPs) on Aristolochia Olivieri (AO) extract as a support and reducing agent is described. Investigation of catalytically activity of obtained catalyst (AO@PdNPs) was performed for the reduction of nitroaromatic compounds. Of note are the functional group tolerance, fast rate, and the ability to apply a scope of nitro compounds (up to 30). The synthesized catalyst was characterized with UV−visible spectra, FE-SEM, EDS, XRD, AAS, FT-IR, and TEM techniques. The corresponding amine product was obtained excellent to high yields. The catalytic activity of AO@ PdNPs for the hydrogenation of 4-methyl-2-nitroaniline and 4-methoxy-2-nitroaniline was pursued by UV-visible spectroscopy which presented excellent activity of catalyst.

Item Type: Article
Uncontrolled Keywords: phytochemicals, palladium nanoparticles, nitro aromatic compounds, reduction, aromatic amines
Subjects: R Medicine > RS Pharmacy and materia medica
Depositing User: ePrints deposit
Date Deposited: 23 Sep 2021 08:46
Last Modified: 23 Sep 2021 08:46
URI: http://eprints.tiu.edu.iq/id/eprint/748

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